{"created":"2023-07-25T10:33:30.092372+00:00","id":4884,"links":{},"metadata":{"_buckets":{"deposit":"99deaab9-d0df-4f37-9f0d-27161018b638"},"_deposit":{"created_by":3,"id":"4884","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"4884"},"status":"published"},"_oai":{"id":"oai:shizuoka.repo.nii.ac.jp:00004884","sets":["122:223"]},"author_link":["5042","5040","809","5041"],"item_26_biblio_info_5":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2011-01-25","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2-3","bibliographicPageEnd":"312","bibliographicPageStart":"308","bibliographicVolumeNumber":"217","bibliographic_titles":[{"bibliographic_title":"Journal of Photochemistry and Photobiology A: Chemistry"}]}]},"item_26_description_30":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_26_description_9":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A quasi-solid gel-polymer electrolyte for dye-sensitized nanostructured TiO2 sensitized by N719 ruthenium dye has been developed. The electrolyte comprises of polyacrylonitrile along with plasticizers, ethylene carbonate and propylene carbonate in the 15:35:50 ratio and the redox couple consists of tetrabutyl ammonium iodide and iodine along with tertiary butyl pyridine. The concentration of iodide:iodine was optimized and optimal activity was found when the molar ratio is 1.50:0.05. This gel electrolyte has a high electrical conductivity of 4.33 mS cm(-1) and overall conversion efficiencies of over 7% were obtained for solar to electrical energy conversion which is higher than the values reported for other similar gel-polymer electrolytes. The reduction in efficiency compared to a solar cell employing a liquid electrolyte can be attributed to incomplete wetting of pores and due to mass transfer limitations of redox species through a more viscous medium.","subitem_description_type":"Abstract"}]},"item_26_publisher_6":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier"}]},"item_26_relation_28":{"attribute_name":"出版者DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.jphotochem.2010.10.024","subitem_relation_type_select":"DOI"}}]},"item_26_relation_34":{"attribute_name":"出版者版","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1016/j.jphotochem.2010.10.024","subitem_relation_type_select":"URI"}}]},"item_26_rights_7":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright © 2010 Elsevier B.V. All rights reserved."}]},"item_26_source_id_19":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"10106030","subitem_source_identifier_type":"ISSN"}]},"item_26_source_id_23":{"attribute_name":"NII書誌ID","attribute_value_mlt":[{"subitem_source_identifier":"AA10684407","subitem_source_identifier_type":"NCID"}]},"item_26_subject_8":{"attribute_name":"NDC","attribute_value_mlt":[{"subitem_subject":"549","subitem_subject_scheme":"NDC"}]},"item_26_version_type_32":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Ileperuma, Oliver A."}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kumara, G. R. Asoka"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yang, Hong-Sheng"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Murakami, Kenji"}],"nameIdentifiers":[{},{},{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-12-14"}],"displaytype":"detail","filename":"110520001.pdf","filesize":[{"value":"322.8 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"110520001.pdf","url":"https://shizuoka.repo.nii.ac.jp/record/4884/files/110520001.pdf"},"version_id":"f464a3c9-eeec-48ea-8472-c864bced4823"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Quasi-solid electrolyte based on polyacrylonitrile for dye-sensitized solar cells","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Quasi-solid electrolyte based on polyacrylonitrile for dye-sensitized solar cells","subitem_title_language":"en"}]},"item_type_id":"26","owner":"3","path":["223"],"pubdate":{"attribute_name":"公開日","attribute_value":"2011-05-22"},"publish_date":"2011-05-22","publish_status":"0","recid":"4884","relation_version_is_last":true,"title":["Quasi-solid electrolyte based on polyacrylonitrile for dye-sensitized solar cells"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2024-02-14T03:01:57.818640+00:00"}